SHERWIN WILLIAMS CO -- 1601 GLOSSY BLACK, SPRAY PAINT -- 8010-00-132-2863
=====================  Product Identification  =====================

Product ID:1601 GLOSSY BLACK, SPRAY PAINT
MSDS Date:01/04/1993
FSC:8010
NIIN:00-132-2863
MSDS Number: BVMYL
=== Responsible Party ===
Company Name:SHERWIN WILLIAMS CO
Address:31500 SOLON RD
City:SOLON
State:OH
ZIP:44139
Country:US
Info Phone Num:800-247-3266
Emergency Phone Num:216-292-7400
CAGE:54626
=== Contractor Identification ===
Company Name:SHERWIN WILLIAMS COMPANY
Address:101 PROSPECT AVE NW
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Phone:216-566-2902
CAGE:54626
Company Name:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVE NW
Box:City:CLEVELAND
State:OH
ZIP:44115-1042
Country:US
Phone:800-251-2486/216-566-2242
CAGE:54636

=============  Composition/Information on Ingredients  =============

Ingred Name:PROPANE. VP: 760
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 13%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT

Ingred Name:PROPANE, 2-METHYL-; (2-METHYLPROPANE)
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: 8%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:TOLUENE  (SARA III). VP: 22
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 2%
OSHA PEL:200 PPM;150 STEL
ACGIH TLV:50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:BENZENE, ETHYL-; (ETHYL BENZENE)  (SARA III). VP: 7.1
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 2%
OSHA PEL:100 PPM;125 STEL
ACGIH TLV:100 PPM;125 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:XYLENE. VP: 5.9
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 8%
OSHA PEL:100 PPM;150 STEL
ACGIH TLV:100 PPM;150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:ACETONE  (SARA III). VP: 180
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 35%
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM;1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE). VP: 70
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 12%
OSHA PEL:N/K 
ACGIH TLV:N/K 
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE)  (SARA
    III). VP: 18
CAS:108-10-1
RTECS #:SA9275000
Fraction by Wt: 1%
OSHA PEL:100 PPM;75 STEL
ACGIH TLV:50 PPM;75 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER;
    (1-METHOXY-2-PROPANOL ACETATE). VP: 1.8
CAS:108-65-6
RTECS #:AI8925000
Fraction by Wt: 8%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:VOLATILE ORGANIC COMPOUNDS: 88%
RTECS #:9999999VO

Ingred Name:SUPP DATA: PRODS MAY CAUSE A HLTH HAZ. SYMPS MAY NOT BE
    IMMED APPARENT. OBTAIN MED ATTENTION.
RTECS #:9999999ZZ

Ingred Name:EFTS OF OVEREXP: TO LIVER, URINARY, BLOOD-FORMING,
    CARDIOVASCULAR, & REPROD SYS. METHYL ETHYL KETONE MAY INCR (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 12: NERV SYS EFTS OF OTHER SOLVS. INTENTIONAL MISUSE BY
    DELIB CONC & INHAL CONTENTS CAN BE HARMFUL/FATAL.(ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13:NOTE: TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM
    REPROD HAZS. SEEK CONSULT FROM APPROP HLTH PROFESSIONALS(ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14:CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS
    INFO . REPORTS HAVE ASSOC RPTD & PRLNGD OCCUP (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15: OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND
    NERVOUS SYSTEM DAMAGE.
RTECS #:9999999ZZ

Ingred Name:OTHER PREC: CONSULT NFPA CODE. USE APPRVD BONDING &
    GROUNDING PROC. CONTENTS UNDER PRESS. DO NOT PUNCTURE, (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17: INCINERATE, OR EXPOSE TO TEMPS >120F. KEEP FROM
    SUNLIGHT, RADIATORS, STOVES, HOT WATER, & OTHER HEAT (ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18: SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE
    INTERNALLY. KEEP OUT OF REACH OF CHILDREN. THIS COATING (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19:MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES
    WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING(ING 21)
RTECS #:9999999ZZ

Ingred Name:ING 20:OR ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS ARE
    LISTED IN ING SECT, APPLICABLE LIMITS FOR NUISANCE(ING 22)
RTECS #:9999999ZZ

Ingred Name:ING 21: DUSTS ARE ACGIH TLV 10 MG/M3 TDUST, OSHA PEL 25
    MG/M3 (TDUST), 5 MG/M3 (RESP)
RTECS #:9999999ZZ

Ingred Name:RESP PROT: WHICH MAY BE GENERATED FROM THIS PRODUCT,
    UNDERLYING PAINTS, OR THE ABRASIVE.
RTECS #:9999999ZZ

Ingred Name:VENT: EXPOSURE LIMITS. REFER TO OSHA STANDARDS 1910.94,
    1910.107, 1910.108.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:EXPOSURE MAY BE BY INHAL &/OR SKIN OR
    EYE CNTCT, DEPENDING ON CNDTNS OF USE. TO MINIMIZE EXPOSURE, FOLLOW
    RECOM FOR PROPER USE, VENT, & PERSON PROT EQUIP. IRRIT OF EYES,
    SKIN & RESP SYS. MAY CAUSE NER V SYS DEPRESSION. EXTREME OVEREXP
    MAY RESULT IN UNCON & POSS DEATH. HDCH, DIZZ, NAUS AND LOSS OF
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLHT HAZ: COORD ARE INDICATIONS OF EXCESS
    EXPOSURE TO VAPS/SPRAY MISTS. REDNESS & ITCHING/BURNING SENS MAY
    INDICATE EYE OR EXCESS SKIN EXPOSURE. CHRONIC: NO INGRED IN THESE
    PRODS IS AN IARC, NTP OR OS HA LISTED CARCIN. PRLNGD OVEREXP TO
    SOLV INGRED IN INGRED SECT MAY CAUSE ADVERSE EFTS (ING 12)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

=======================  First Aid Measures  =======================

First Aid:INHAL: REMOVE FROM EXPOSURE, RESTORE BREATHING. KEEP WARM &
    QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP & WATER.
    REMOVE CONTAM CLOTHING & LAUNDER BEFORE RE-USE. EYE: FLUSH EYES
    W/LRG AMTS OF  WATER FOR @ LST 15 MIN. GET MED ATTN. INGEST: GET
    MEDICAL ATTENTION.

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:0F,<-18C
Lower Limits:0.9%
Upper Limits:13.1%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
    . IF WATER IS USED, FOG NOZZ PREFERABLE. WATER MAY BE USED TO COOL
    CLSD CNTNRS TO PREVENT PRESS (SUPP DATA)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
    HEAT, ELEC EQUIP, SPARKS, & OPEN FLAME. CLOSED CNTNRS MAY EXPLODE
    WHEN EXPOSED TO EXTREME HEAT. APPLIC TO HOT (SUPP DATA)

==================  Accidental Release Measures  ==================

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
    REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP
    & SPRAY MIST. AVOID CONTACT W/SKIN & EYES. WASH HANDS AFTER USING.
    CONTENTS ARE FLAMM.
Other Precautions:KEEP AWAY FROM HEAT, SPARKS, & OPEN FLAME. DURING USE
    & UNTIL ALL VAPS ARE GONE: KEEP AREA VENT. DO NOT SMOKE. EXTING ALL
    FLAMES, PILOT LIGHTS, & HEATERS. TURN OFF STOVES, ELECTRIC TOOLS
    APPLIANCES, &  ANY OTHER SOURCES OF IGNIT. (ING 17)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
    APPLIC LIMITS BY VENT, WEAR NIOSH/MSHA APPROVED PROPERLY FITTED
    ORGANIC VAP/PARTICULATE RESP. WHEN SANDING/ABRADING THE DRIED FILM,
    WEAR NIOSH/MSHA APPR VD DUST/MIST RESP FOR DUST (ING 23)
Ventilation:LOC EXHST PREFERABLE. GEN EXHST ACCEPTABLE IF THE EXPOSURE
    TO MATLS IN INGRED SECT IS MAINTAINED BELOW APPLIC (ING 24)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
THIS IS A REFORMULATION: PART NUMBER INDICATOR "C" DENOTES NEWER
    PRODUCT THAN "B", 8010-00-132-2863. INGREDS & OTHER CHANGES MAY
    APPLY . FIRE FIGHT PROC: BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXP
    OSED TO EXTREME HEAT. EXPLO HAZ: SURFS REQUIRES SPECIAL PRECS.
    DURING EMER CNDTNS OVEREXP TO DECOMP (ING 11)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:>0F,>-18C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
    MONOXIDE, OXIDES OF METALS IN INGREDIENTS.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA
    40 CFR 261. WASTE MUST BE TESTED FOR IGNIT TO DETERMINE APPLIC EPA
    HAZ WASTE NO. INCINERATE IN APPRVD FACILITY. DO NOT INCINERATE CLSD
    CNTNR. DISP OF I /A/W FED, STATE & LOC REGS REGARDING POLLUTION.

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