Material Safety Data Sheet
1-Pentanol, 99%

ACC# 01035
Section 1 - Chemical Product and Company Identification

MSDS Name: 1-Pentanol, 99%
Catalog Numbers: AC160600000, AC160600010, AC160600025, AC160600250, NC9119814, XXAC16060-200L
Synonyms:
n-Amyl alcohol; Pentyl alcohol
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
71-41-01-Pentanol 99% 200-752-1

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: colorless clear liquid. Flash Point: 49 deg C.
Hygroscopic (absorbs moisture from the air).
Target Organs: Central nervous system, lungs, nerves.


Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation.
Ingestion: May cause irritation of the digestive tract. May cause central nervous system depression. May cause burning sensations, coughing, wheezing, laryngitis, shortness of breath and headache.
Inhalation: Harmful if inhaled. Causes respiratory tract irritation. May cause narcotic effects in high concentration. Inhalation may produce burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
Chronic: Not available.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Get medical aid. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: 49 deg C ( 120.20 deg F)
Autoignition Temperature: 300 deg C ( 572.00 deg F)
Explosion Limits, Lower:1.30 vol %
Upper: 10.50 vol %
NFPA Rating: (estimated) Health: 1; Flammability: 3; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Use a spark-proof tool.

Section 7 - Handling and Storage


Handling: Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Take precautionary measures against static discharges. Use only in a chemical fume hood.
Storage: Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
1-Pentanol none listed none listed none listed

OSHA Vacated PELs: 1-Pentanol: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Not available.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Clear liquid
Appearance: colorless
Odor: stench
pH: 7(25g/l aq.sol.)
Vapor Pressure: 2.6 mbar @ 20 deg C
Vapor Density: 3.0 (air=1)
Evaporation Rate:0.18 (butyl acetate=1)
Viscosity: 4 mPas @ 20 deg C
Boiling Point: 137 - 139 deg C @ 760 mmHg
Freezing/Melting Point:-78 deg C
Decomposition Temperature:Not available.
Solubility: 22 g/l in water (20C)
Specific Gravity/Density:.8110g/cm3
Molecular Formula:C5H12O
Molecular Weight:88.15

Section 10 - Stability and Reactivity


Chemical Stability: Stable.
Conditions to Avoid: Incompatible materials, ignition sources, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials: Strong oxidizing agents, alkali metals, alkaline earth metals.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 71-41-0: SB9800000
LD50/LC50:
CAS# 71-41-0:
     Draize test, rabbit, eye: 81 mg Severe;
     Draize test, rabbit, eye: 5 uL/24H Severe;
     Draize test, rabbit, skin: 3200 mg/24H Severe;
     Draize test, rabbit, skin: 20 mg/24H Moderate;
     Oral, mouse: LD50 = 200 mg/kg;
     Oral, mouse: LD50 = 200 mg/kg;
     Oral, rat: LD50 = 5660 uL/kg;
     Oral, rat: LD50 = 370 mg/kg;
     Skin, rabbit: LD50 = 2830 uL/kg;
Carcinogenicity:
CAS# 71-41-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: Daphnia: LC50 = 18.0 mg/L; 48H; .Algae: LC50 = 18.0 mg/L; 96H; .Bacteria: LC50 = 18.0 mg/L; 17H; . log POW = 1.30
Environmental: No information available.
Physical: No information available.
Other: Biodegradable. Avoid entering into waters or underground water. Do not empty into drains.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: PENTANOLS AMYL ALCOHOLS
Hazard Class: 3 3
UN Number: UN1105 UN1105
Packing Group: III II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 71-41-0 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 71-41-0: acute, chronic, flammable.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 71-41-0 can be found on the following state right to know lists: New Jersey, Pennsylvania, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN
Risk Phrases:

     R 10 Flammable.
     R 20 Harmful by inhalation.

Safety Phrases:

     S 24/25 Avoid contact with skin and eyes.

WGK (Water Danger/Protection)

     CAS# 71-41-0: 1
Canada - DSL/NDSL
     CAS# 71-41-0 is listed on Canada's DSL List.
Canada - WHMIS
     This product does not have a WHMIS classification.
Canadian Ingredient Disclosure List
     CAS# 71-41-0 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 7/20/1998
Revision #4 Date: 6/10/2003

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.